An efficient palladium-cocatalyst system for vinylation of unsaturated carboxylic acid has been exploited,among which aliphatic amines(ALA)are firstly used as cocatalysts.
The processes about zymohydrolysis of lipase, microbiological conversion of fatty acid and fattyalcohol,production of unsaturated fatty acid by microbe,are introduced.
Unsaturated transition metal thiocarbonyl complexes are building blocks for stable organometallic complexes and play important role in catalysis and biology.The CS molecule is isovalent with CO.