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Triaminoguanidine is a kind of non-azide nitrogen-rich flammable compound, which has some advantages of high nitrogen, good thermal stability, and high positive formation enthalpy, etc.

摘要三氨基胍是一种非叠型、可燃性化合,其系列含能化合有高的正生成焓、热稳定性好、含量高等特点。

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So, the formula for enthalpy is usually written as change in enthalpy.

因此,的公式通常写

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It's analogous to the standard enthalpy of formation that we use to calculate change in enthalpy.

它类似于我们用来计算的标准生

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These measurements are done at standard conditions, which we discussed in the enthalpy and entropy episodes.

这些测是在标准条件下完的, 我们在和熵情节中对此进行了讨论。

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And I'm very happy the inventors knew how to calculate the enthalpy change of chemical reactions.

我很高兴发明者知道如何计算化学反应的

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And we measure enthalpy with a weird little science called calorimetry.

我们用一种叫做热法的奇怪小科学来测

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Why enthalpy change is different from heat, even though they turn out to be pretty much the same anyway.

为什么与热不同, 尽管事实证明它们几乎是一样的。

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Those bonds are nothing but energy, and using enthalpy, we can measure how much energy they have.

这些键只不过是能, 使用,我们可以测它们有多少能

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Change in enthalpy is equal to the heat gained or lost by the system.

等于系统获得或损失的热

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The law itself says nothing about the standard enthalpy of formation.

该定并未提及标准生

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So I guess in the capital H for enthalpy does kinda make sense.

所以我想在大写的 H 中表示确实有点道理。

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So, I wonder how that compares to the amount we would predict using Hess's Law and the standard enthalpy of formation?

所以,我想知道这与我们使用赫斯定和标准生预测的相比如何?

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Note that the standard enthalpy is in kilojoules while the standard entropy is in joules per Kelvin.

请注意,标准的单位是千焦耳, 而标准熵的单位是焦耳每开尔文。

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Hess' Law is often stated in terms of standard enthalpies of formation.

赫斯定通常用标准生来表述。

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As long as you start with the same reactants and end with the same products, the enthalpy change is the same.

只要您从相同的反应物开始并以相同的产物结束, 就相同。

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Thanks to many hardworking chemists, the standard enthalpy of formation has been measured for hundreds of compounds.

感谢许多辛勤工作的化学家,已经测了数百种化合物的标准生

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First, we'll find the enthalpy change using Hess's Law and standard enthalpies of formation.

首先, 我们将使用赫斯定和标准生求出

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Hopefully that sounds like fun because more about the ins and outs of this are coming in an episode on how to measure enthalpy.

希望这听起来很有趣,因为有关如何测的一集中将详细介绍这方面的来龙去脉。

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A large change in enthalpy can determine the direction of a free energy change, even if the entropy changes in the opposite direction, and vice versa.

的大化可以决定自由能化的方向,即使熵的化方向相反, 反之亦然。

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In order to study this stuff carefully, he looked at the standard enthalpies of formation of the reactants and the products of a reaction.

为了仔细研究这些东西,他研究了反应物和反应产物的标准生

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When we plug the standard enthalpies of formation into the formula and do the math, we find that the change in standard enthalpy is plus 166 kilojoules.

当我们将标准生代入公式并进行计算时,我们发现标准生化是加上 166 千焦耳。

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