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The key step of the synthesis of chroman derivatives is to construct chiral chroman ring.

合成色满衍生物的关键构建含有中心的色满环。

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They are all chiral molecules and belong in the racemate.

它们都分子,属于外消旋体。

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Several chiral aryl diphosphite ligands derived from pyranoside backbones of glucose and galactose were applied in Rh-catalyzed asymmetric hydroformylation of styrene.

合成四个从葡萄糖及半乳糖衍生的手芳基双膦配体,制备双膦-铑(Ⅰ)配合物催化剂,并将其用于苯乙烯不对称氢甲酰化反应中。

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Three strategies (additive, chiral auxiliary or chiral reagent) were developed to improve the diastereoselectivity or enantioselectivity of the ylide cyclopropanation reactions.

通过添加剂、手基、手试剂等3种策略,分别控制反应的非对映选择和对映选择

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A set of structurally close chiral arylalcohols and achiral arylalcohols were studied using chiralcel OD-H column as stationary phase.

采用高效液相色谱法对15种芳香醇及结构相近化合物进行分离研究。

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In this paper, (S)- ethyl mandelate was obtained through chiral resolution of racemic ethyl mandelate by lipase.

扁桃酸乙酯合成扁桃酸系列药物的重要中间体。

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A chiral hadronic model is extended to investigate antikaon condensation and hyperons production of protoneutron stars.

摘要用相对论平均场下的手徵强子模型研究前中子星内(平均值)K凝聚和超子的生成。

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2021诺贝尔得主访谈录

So, we have a transfer of the chiral information from the catalyst to the products.

信息从催化剂转移到了产物上。

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Scishow 精选系列

In thalidomide, for example, the chiral center is a carbon atom attached to one of the rings.

例如在萨力多胺中,性中心吸附在一环上的碳原子。

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A chiral molecule has an atom—typically carbon—with four different groups attached to it.

分子有一原子——典型的碳原子——有四不同的组吸附原子上。

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2021诺贝尔得主访谈录

An asymmetric organocatalysis that means that the catalyst, our small well-defined organic catalyst is asymmetric, that it's chiral.

不对称有机催化也就说,们的小而明确的有机催化剂不对称的,手性的。

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2021诺贝尔得主访谈录

And in the same way, as our hands are chiral, molecules can be chiral.

同样的,手手性的,分子也可以手性的。

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If you position the version of the molecule that's considered " right-handed" , called the R enantiomer, so the closest oxygen atom to the chiral center is below it, the hydrogen atom attached to the center will be facing away from you.

如果你找到了“右撇子”的分子变体,即R对映体,那么离手性中心最近的氧原子就在它的下方,附在中心的氢原子将背朝你。

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Thalidomide, which is made up of three connected rings of carbon and nitrogen atoms, plus some oxygen and hydrogen, is what's known as a chiral molecule.

萨力多胺,由三碳原子和氮原子的连接环以及一些氧和氢组成,也被称分子。

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2021诺贝尔得主访谈录

So, our hands are mirror images of each other, they are chiral because we cannot put one on top of the other and make them look identical.

们的手彼此的镜像,它们手性的,它们并不完全重合。

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Chiral comes from the Greek for hand or claw, and chemists often think of chiral molecules as being right-handed or left-handed.

手性一词来源于希腊指手或爪,化学家们通常将手性分子当成右撇子或左撇子。

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Scishow 精选系列

And that's because the different versions of chiral molecules—called enantiomers —are made up of all the same parts, but arranged differently.

分子的不同变体——即对映体——由所有相同部分组成,但却以不同形式排列。

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SciShow - Chemistry

These groups are kind of like your fingers: in each enantiomer, the groups are attached to the chiral center in the opposite order, so they’re mirror images of each other.

这些基团有点像你的手指: 在每对映异体中,这些基团以相反的顺序附着在手中心, 所以它们彼此的镜像。

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Lex Fridman Podcast

In two, but molecules can have more than one chiral center, and that's not the only stereosometry that they can have.

在二维中, 但分子可以拥有不止一中心,这并非它们唯一的立体化学性质。

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Lex Fridman Podcast

So the point of this sort of chiral transition that I'm putting out is chirality is actually a signature of being in a complex chemical space.

因此,提出的这种转变的核心在于,手性实际上存在于复杂化学空间中的一标志。

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SciShow - Chemistry

And that’s because the different versions of chiral molecules — called enantiomers — are made up of all the same parts, but arranged differently.

不同版本的手性分子— — 称对映体—— 由所有相同的部分组成, 但排列不同。

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Lex Fridman Podcast

You push your molecules to a large enough complexity that chiral molecules become very likely to form.

你将分子复杂度提高到一定程度,分子就非常有可能形成。

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Lex Fridman Podcast

And then there's a cascade of molecular recognition where chiral molecules can recognize each other.

,分子识别过程如瀑布般层层递进,其中分子能够彼此识别。

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Lex Fridman Podcast

But if you get to this threshold boundary, above that boundary, almost every single molecule is chiral.

但一旦跨越这一阈值边界,在边界之上,几乎所有分子都具有

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Lex Fridman Podcast

People take for granted the existence of chiral molecules at all, that this property of having a handedness, and they just assume that it's just a generic feature of chemistry.

人们理所当然地分子存在的,这种具有手性的特性,他们只假设这化学的一普遍特征。

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