Dicyano 9,10 dihydro 9,10 ethenoanthracene(4) was synthesized by addition reation of acetylenedinitrile and anthracene. Concave tetrazaporphyrin has been obtained from the four molecules of 4.

乙炔与蒽环加成反应合成了11,12--9,10--9,10-亚乙基蒽(4),44身加成聚合制备了一种全新凹型四氮杂口卜啉结构化合物。