Four compounds of phosphite ester and phosphoramide containing azido groups were synthesized. The molecular structure of the products has been confirmed by IR，1HNMR，FAB-MS and elemental analysis.

首次叠氮亚磷酸酯及叠氮磷胺类化物，并用IR、1HNMR、FAB-MS及元素化物结构进行鉴定。