hydroformylation

Several chiral aryl diphosphite ligands derived from pyranoside backbones of glucose and galactose were applied in Rh-catalyzed asymmetric hydroformylation of styrene.

合成了四个从葡萄糖及半乳糖衍的手芳基双膦配体,制备了手双膦-铑(Ⅰ)配合物催剂,并将其用于苯乙烯不对称氢甲酰反应中。