Desorption chemical ionization mass spectrometry of twelve metallohematoporphyrin complexes has been investigated under DEP condition using mixture of tetramethylsilane and methane as regent gas.
本文以四甲基硅烷/甲烷混合反应气,DEP术,测定12个金属血卟啉络合物的解吸化学电离质谱。
Desorption chemical ionization mass spectrometry of twelve metallohematoporphyrin complexes has been investigated under DEP condition using mixture of tetramethylsilane and methane as regent gas.
本文以四甲基硅烷/甲烷混合反应气,DEP术,测定12个金属血卟啉络合物的解吸化学电离质谱。
Based on these results and the ESI-MS data, the mechanism of sulfoxidation was proposed to be intramolecular nucleophilic oxygen transfer to a coordinated sulfide.
基于这些结果和电喷雾质谱(ESI-MS)据,亚砜化反应的机理推测为分子内亲核氧转移到络合的硫醚底物上。
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