Sodium phenolate and acetophenone can be obtained by adding sodium hydrate into azeotrope.
共沸物中加入氢氧化钠,分离出酚钠盐和苯乙酮。
Sodium phenolate and acetophenone can be obtained by adding sodium hydrate into azeotrope.
共沸物中加入氢氧化钠,分离出酚钠盐和苯乙酮。
The primary synthetic methods of 4-hydroxycoumarin was reviewed starting from phenol, 2-acetylsalicylic acid, methyl salicylate, and o-hydroxyacetophenone respectively.
概述了4-羟基

的合成方法,重点介绍了苯酚法,乙酰水杨酸法,水杨酸甲酯法,邻羟基苯乙酮法。
The phenols were O-alkylated with 100% conversion and 100% selectivities using phenacyl bromide and benzyl bromide as alkylating reagents.
用
代苯乙酮和
苄
烷基化试剂,以高产率和100%的转化率以及100%的选择性得到了酚的O-烷基化产物。
Phenoxyacetophenone could be prepared from potassium phenolate and m bromoacetophenone via Ullmann reaction catalyzed by copper acetate in high yields.
苯氧基苯乙酮可由酚钾

苯乙酮在醋酸铜催化下以高产率合成。
P-hydroxyacetophenone combined with methyl chloroacetate can get a new acetonate.This new acetonate combined with another compound-ethanolamine and get a new schiff base.
由对羟基苯乙酮
氯乙酸甲酯反应,得到一种酮,这种酮再
乙醇胺反应得到一种新的希夫碱。
Firstly, p-methylacetophenone was obtained in the presence of alchlor as the catalyst, and the optimum condition was 4:1:2 in molar ratio for toluene, acetic anhydride and alchlor with yield of 86.2%.
首先,以甲苯和乙酸酐
原料,在催化剂三氯化铝存在下合成对甲基苯乙酮,并确定甲苯,乙酸酐和三氯化铝的最佳摩尔比
4: 1: 2,收率
86.2%。
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