N-phosphoryl amino acids could be catalyzed by imidazole to result in solvolysis such as ester exchanges on phosphorus, esterification, formation of peptides and N→O migration of the phosphoryl group.
咪对磷酰
氨基酸的活
反应具有较强的
作用,磷酰
丝、苏氨酸在咪
下不仅能发生
剂解反应,如磷
换、羧基活
成
、成肽及磷酰基的N→O迁移等,而且还会发生分子内环
反应;